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Physical Chemistry I

物理化學(一)

本課程是由 國立陽明交通大學應用化學系提供。

本學期將使學生瞭解化學熱力學的基礎觀念及應用 ，並藉上課及作業訓練學生建立觀念及培養學生獨立思考的能力，希望同學在學習後能墊定扎實的化學基礎。

課程用書：Physical Chemistry, R. G. Mortimer, 3rd Ed. Academic Press (2008)，偉明圖書.
為求學習成效完美，請購買課本！

 

授課教師 應用化學系 李遠鵬老師
課程學分 4學分
授課年度 影音：97學年度拍攝、99學年度2修；講義：99學年度更新
授課對象 大學二年級學生
預備知識 物理、化學、應用數學
課程提供 課程影音   課程綱要   課程行事曆   課程講義

週次課程內容課程影音課程下載
課程概述：如何學好物理化學線上觀看MP4下載
導論：物理化學各領域的關係線上觀看MP4下載
第一章 Systems, States, and Processes
1-1-1-2 一些基本的單位定義及觀念		線上觀看MP4下載
1-3 對氣體的描述：理想氣體及真實氣體線上觀看MP4下載
1-4 PVT surface及臨界點線上觀看MP4下載
1-5 熱力學所需之數學線上觀看MP4下載
第二章 The Equilibrium Macroscopic States of Gases and Liquids
2-1-2-2 熱力學的簡單發展史及功與熱		線上觀看MP4下載
2-3 Internal Energy：The First Law of Thermodynamics
2-4 Calculation of Amounts of Heat and Energy Changes
2-5 Enthalpy		線上觀看MP4下載
2-5 Enthalpy
2-6 Application to Ideal Gas
2-7 Application to Non-Ideal Gas		線上觀看MP4下載
2-8 Calculation of Enthalpy Changes of Process without Chemical Reaction線上觀看MP4下載
第三章 Second and Third Laws of Thermodynamics: Entropy
3-1 The Second Law of Thermodynamics and the Carnot Engine		線上觀看MP4下載
3-2 The Mathematical Statement of the Second Law: Entropy線上觀看MP4下載
3-3 The Calculation of Entropy Changes
3-4 Statistical Entropy
3-5 Third Law of Thermodynamics and Absolute Entropies		線上觀看MP4下載
第四章 The Second and Third Laws of Thermodynamics：Entropy
4.1-4.2 G(Gibbs)和A(Helmholtz)自由能及動力學的基礎公式 		線上觀看MP4下載
4-4 Gibbs Energy Calculation線上觀看MP4下載
4-5 Multicomponent System
4-6 Euler's Theorem and the Gibbs-Duhem Relation		線上觀看MP4下載
第五章 The Thermodynamics of Real Systems
5-1 The Fundamental Fact of Phase Equilibrium
5-2 The Gibbs Phase Rule
5-3 Phase equilibrium in 1-component systems
5-4 The Gibbs Energy and Phase Transitions		線上觀看MP4下載
5-4 The Gibbs Energy and Phase Transitions
5-5 Surface in One-Component System		線上觀看MP4下載
第六章 The Thermodynamics of Solutions
6-1 Ideal Solutions		線上觀看MP4下載
6-2 Henrys Law and Dilute Nonelectrolyte Solution
6-3 Activity and activity coefficients		線上觀看MP4下載
6-5 Thermodynamic Functions of Nonideal Solutions
6-6 Phase Diagrams of Non-ideal mixtures
6-7 Colligative (tied together) Properties(依數性質)		線上觀看MP4下載
第七章 Chemical Equilibrium
7-1 ΔG and the Equilibrium Constant
7-2 Reactions Involving Gases and Pure Solids or Liquids
7-3 Chemical Equilibrium in Solutions		線上觀看MP4下載
7-4 Debye-Hückel Theory
7-5 Buffer Solutions
7-6 Temp. Dependence
7-7 Biological Systems		線上觀看MP4下載
第八章 The Thermodynamics of Electrochemical Systems
8-1 The Chemical Potential and the Electric Potential
8-2 Electrochemical Cells
8-3 Half-cell Potentials and Cell Potentials		線上觀看MP4下載
8-4 Determination of a± and g ± of Electrolytes
8-5 Determination of pH
8-6 Thermodynamic for Electrochemistry
8-6 Ion Mobility and Transference Number (補充)		線上觀看MP4下載

課程目標

本課程上課較為進階，以理學院學士班學生為優先。藉上課及作業訓練學生建立觀念及培養學生獨立思考的能力，並使學生瞭解化學熱力學的基礎觀念及應用。

課程章節

章節 章節內容
第一章Systems, States, and Processes
第二章The Equilibrium Macroscopic States of Gases and Liquids
第三章Work, Heat, and Energy：The First Law of Thermodynaics　
第四章The Second and Third Laws of Thermodynamics：Entropy
第五章The Thermodynamics of Real Systems
第六章Phase Equilbrium
第七章Multicomponent Systems
第八章The Thermodynamics of Chemical Equilibrium
第九章The Thermodynamics of Electrical Systems


課程書目

Physical Chemistry, R. G. Mortimer, 3rd Ed. Academic Press (2008)，偉明圖書。

參考書目

P. W. Atkins, "Physical Chemistry", 7th Ed., 2002, Oxford.
R. A. Alberty & R. J. Silbey, "Physical Chemistry", 4th Ed., Wiley, 2005.
I. N. Levine, "Physical Chemistry", 5th Ed., 2002.
J. S. Winn, "Physical Chemistry", 1st Ed., 1995, Harper Collins.
J. H. Noggle, "Physical Chemistry", 3rd Ed., Scott/Foresman, 1996 (Mathcad).
I. M. Klotz & R. M. Rosenberg, "Chemical Thermodynamics", 6th Ed., Wiley, 2000. (建議初學者研讀)
G. N. Lewis & M. Randall (Revised by K. S. Pitzer & L. Brewer), "Thermodynamics", 1961. (進階者用)
H. B. Callen, "Thermodynamics", 1960 (1988). (由數學觀點處理)
R. S. Berry, S. A. Rice, and J. Ross, "Physical Chemistry", 1980, Wiley. (進階)
I. Tinoco et al. "Physical Chemistry: Principles and Applications in Biological Sciences", 4th Ed., 2001. (生科應用)

評分標準

項目百分比
第一次小考
(第1-3章(10/14；考1小時))		10%
期中考
(第1-4章(11/3；19:00~24:00))		30%
第二次小考
(第5-7章 (12/23；考2小時))		15%
期末考
(第5-9章(1/12；19:00~24:00))		40%
作業15%

本課程行事曆提供課程進度與考試資訊參考。

學期週次
上課日期
參考課程進度

第一週

09/12, 09/16
  • Chapter 1 The Behavior of Gases and Liquids
第二週09/22, 09/23
  • Chapter 1 The Behavior of Gases and Liquids
第三週09/29, 09/30
  • Chapter 2 Work, Heat and Energy：The First Law
第四週10/06, 10/07
  • Chapter 2 Work, Heat and Energy：The First Law
第五週10/13, 10/14
  • Chapter 3 Second and Third Laws of Thermodynamics: Entropy
    10/14 第一次小考
第六週10/20, 10/21
  • Chapter 3 Second and Third Laws of Thermodynamics: Entropy
第七週10/27, 10/28
  • Chapter 4 The Thermodynamics of Real Systems
第八週11/03, 11/04
  • 期中考
第九週11/10, 11/11
  • Chapter 4 The Thermodynamics of Real Systems
第十週11/17, 11/18
  • Chapter 5 Phase Equilibrium
第十一週11/24, 11/25
  • Chapter 5 Phase Equilibrium
第十二週12/01, 12/02
  • Chapter 6 The Thermodynamics of Solutions
第十三週12/08, 12/09
  • Chapter 6 The Thermodynamics of Solutions
第十四週12/15, 12/16
  • Chapter 6 The Thermodynamics of Solutions
第十五週12/22, 12/23
  • Chapter 7 Chemical Equilibrium
第十六週12/29, 12/30
  • Chapter 8 The Thermodynamics of Electrochemical Systems
    12/23 第二次小考
第十七週01/05, 01/06
  • Chapter 8 The Thermodynamics of Electrochemical Systems
第十八週01/12, 01/13
  • 期末考

課程講義 Course Handout

章節 下載連結
Chapter 1PDF
Chapter 2PDF
Chapter 3PDF
Chapter 4PDF
Chapter 5PDF
Chapter 6PDF
Chapter 7PDF
Chapter 8PDF
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