物理化學(一) Physical Chemistry I | 應用化學系李遠鵬老師

Physical Chemistry I

物理化學(一)

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課程影音
課程綱要
課程行事曆
課程講義

本學期將使學生瞭解化學熱力學的基礎觀念及應用，並藉上課及作業訓練學生建立觀念及培養學生獨立思考的能力，希望同學在學習後能墊定扎實的化學基礎。

課程用書：Physical Chemistry, R. G. Mortimer, 3rd Ed. Academic Press (2008)，偉明圖書.
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授課教師	應用化學系李遠鵬老師
課程學分	4學分
授課年度	影音：97學年度拍攝、99學年度2修；講義：99學年度更新
授課對象	大學二年級學生
預備知識	物理、化學、應用數學
課程提供	課程影音課程綱要課程行事曆課程講義

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搜尋:

課程內容	課程影音	課程下載
課程概述：如何學好物理化學	線上觀看	MP4下載
導論：物理化學各領域的關係	線上觀看	MP4下載
第一章 Systems, States, and Processes 1-1-1-2 一些基本的單位定義及觀念	線上觀看	MP4下載
1-3 對氣體的描述：理想氣體及真實氣體	線上觀看	MP4下載
1-4 PVT surface及臨界點	線上觀看	MP4下載
1-5 熱力學所需之數學	線上觀看	MP4下載
第二章 The Equilibrium Macroscopic States of Gases and Liquids 2-1-2-2 熱力學的簡單發展史及功與熱	線上觀看	MP4下載
2-3 Internal Energy：The First Law of Thermodynamics 2-4 Calculation of Amounts of Heat and Energy Changes 2-5 Enthalpy	線上觀看	MP4下載
2-5 Enthalpy 2-6 Application to Ideal Gas 2-7 Application to Non-Ideal Gas	線上觀看	MP4下載
2-8 Calculation of Enthalpy Changes of Process without Chemical Reaction	線上觀看	MP4下載
第三章 Second and Third Laws of Thermodynamics: Entropy 3-1 The Second Law of Thermodynamics and the Carnot Engine	線上觀看	MP4下載
3-2 The Mathematical Statement of the Second Law: Entropy	線上觀看	MP4下載
3-3 The Calculation of Entropy Changes 3-4 Statistical Entropy 3-5 Third Law of Thermodynamics and Absolute Entropies	線上觀看	MP4下載
第四章 The Second and Third Laws of Thermodynamics：Entropy 4.1-4.2 G(Gibbs)和A(Helmholtz)自由能及動力學的基礎公式	線上觀看	MP4下載
4-4 Gibbs Energy Calculation	線上觀看	MP4下載
4-5 Multicomponent System 4-6 Euler's Theorem and the Gibbs-Duhem Relation	線上觀看	MP4下載
第五章 The Thermodynamics of Real Systems 5-1 The Fundamental Fact of Phase Equilibrium 5-2 The Gibbs Phase Rule 5-3 Phase equilibrium in 1-component systems 5-4 The Gibbs Energy and Phase Transitions	線上觀看	MP4下載
5-4 The Gibbs Energy and Phase Transitions 5-5 Surface in One-Component System	線上觀看	MP4下載
第六章 The Thermodynamics of Solutions 6-1 Ideal Solutions	線上觀看	MP4下載
6-2 Henrys Law and Dilute Nonelectrolyte Solution 6-3 Activity and activity coefficients	線上觀看	MP4下載
6-5 Thermodynamic Functions of Nonideal Solutions 6-6 Phase Diagrams of Non-ideal mixtures 6-7 Colligative (tied together) Properties(依數性質)	線上觀看	MP4下載
第七章 Chemical Equilibrium 7-1 ΔG and the Equilibrium Constant 7-2 Reactions Involving Gases and Pure Solids or Liquids 7-3 Chemical Equilibrium in Solutions	線上觀看	MP4下載
7-4 Debye-Hückel Theory 7-5 Buffer Solutions 7-6 Temp. Dependence 7-7 Biological Systems	線上觀看	MP4下載
第八章 The Thermodynamics of Electrochemical Systems 8-1 The Chemical Potential and the Electric Potential 8-2 Electrochemical Cells 8-3 Half-cell Potentials and Cell Potentials	線上觀看	MP4下載
8-4 Determination of a± and g ± of Electrolytes 8-5 Determination of pH 8-6 Thermodynamic for Electrochemistry 8-6 Ion Mobility and Transference Number (補充)	線上觀看	MP4下載

目前顯示第 1 至第 25 個資料列，總計 25 個資料列

課程目標

本課程上課較為進階，以理學院學士班學生為優先。藉上課及作業訓練學生建立觀念及培養學生獨立思考的能力，並使學生瞭解化學熱力學的基礎觀念及應用。

課程章節

章節	章節內容
第一章	Systems, States, and Processes
第二章	The Equilibrium Macroscopic States of Gases and Liquids
第三章	Work, Heat, and Energy：The First Law of Thermodynaics
第四章	The Second and Third Laws of Thermodynamics：Entropy
第五章	The Thermodynamics of Real Systems
第六章	Phase Equilbrium
第七章	Multicomponent Systems
第八章	The Thermodynamics of Chemical Equilibrium
第九章	The Thermodynamics of Electrical Systems

課程書目

Physical Chemistry, R. G. Mortimer, 3rd Ed. Academic Press (2008)，偉明圖書。

參考書目

P. W. Atkins, "Physical Chemistry", 7th Ed., 2002, Oxford.
R. A. Alberty & R. J. Silbey, "Physical Chemistry", 4th Ed., Wiley, 2005.
I. N. Levine, "Physical Chemistry", 5th Ed., 2002.
J. S. Winn, "Physical Chemistry", 1st Ed., 1995, Harper Collins.
J. H. Noggle, "Physical Chemistry", 3rd Ed., Scott/Foresman, 1996 (Mathcad).
I. M. Klotz & R. M. Rosenberg, "Chemical Thermodynamics", 6th Ed., Wiley, 2000. (建議初學者研讀)
G. N. Lewis & M. Randall (Revised by K. S. Pitzer & L. Brewer), "Thermodynamics", 1961. (進階者用)
H. B. Callen, "Thermodynamics", 1960 (1988). (由數學觀點處理)
R. S. Berry, S. A. Rice, and J. Ross, "Physical Chemistry", 1980, Wiley. (進階)
I. Tinoco et al. "Physical Chemistry: Principles and Applications in Biological Sciences", 4th Ed., 2001. (生科應用)

評分標準

項目	百分比
第一次小考 (第1-3章(10/14；考1小時))	10%
期中考 (第1-4章(11/3；19:00~24:00))	30%
第二次小考 (第5-7章 (12/23；考2小時))	15%
期末考 (第5-9章(1/12；19:00~24:00))	40%
作業	15%

本課程行事曆提供課程進度與考試資訊參考。

學期週次	上課日期	參考課程進度
第一週	09/12, 09/16	Chapter 1 The Behavior of Gases and Liquids
第二週	09/22, 09/23	Chapter 1 The Behavior of Gases and Liquids
第三週	09/29, 09/30	Chapter 2 Work, Heat and Energy：The First Law
第四週	10/06, 10/07	Chapter 2 Work, Heat and Energy：The First Law
第五週	10/13, 10/14	Chapter 3 Second and Third Laws of Thermodynamics: Entropy 10/14 第一次小考
第六週	10/20, 10/21	Chapter 3 Second and Third Laws of Thermodynamics: Entropy
第七週	10/27, 10/28	Chapter 4 The Thermodynamics of Real Systems
第八週	11/03, 11/04	期中考
第九週	11/10, 11/11	Chapter 4 The Thermodynamics of Real Systems
第十週	11/17, 11/18	Chapter 5 Phase Equilibrium
第十一週	11/24, 11/25	Chapter 5 Phase Equilibrium
第十二週	12/01, 12/02	Chapter 6 The Thermodynamics of Solutions
第十三週	12/08, 12/09	Chapter 6 The Thermodynamics of Solutions
第十四週	12/15, 12/16	Chapter 6 The Thermodynamics of Solutions
第十五週	12/22, 12/23	Chapter 7 Chemical Equilibrium
第十六週	12/29, 12/30	Chapter 8 The Thermodynamics of Electrochemical Systems 12/23 第二次小考
第十七週	01/05, 01/06	Chapter 8 The Thermodynamics of Electrochemical Systems
第十八週	01/12, 01/13	期末考

課程講義 Course Handout

章節	下載連結
Chapter 1	PDF
Chapter 2	PDF
Chapter 3	PDF
Chapter 4	PDF
Chapter 5	PDF
Chapter 6	PDF
Chapter 7	PDF
Chapter 8	PDF