Physical Chemistry (I)

物理化學(一)

本課程是由 國立陽明交通大學應用化學系提供。

本課程談論化學熱力學,熱力學討論熱或能量流動所造成的系統變化。在巨觀上將討論internal energy (U), enthalpy (H), entropy (S), free energy (G)與系統變化的關係,而微觀上則將介紹系統能量變化對分子運動與系統亂度的影響。在清楚了解U,H,S,G等熱力學參數後,則將進一步提升系統的複雜度,討論如何使用熱力學參數描述多組成(multiple components)或多相(multiple phases)並存系統的的變化與平衡。本課程將藉上課及作業協助學生建立熱力學觀念,並學習使用熱力學參數來對系統與變化進行描述。

課程用書:Physical Chemistry- Quanta, Matter, and Change, 2nd Ed. Peter Atkins, Julio de Paula, Ronald Friedman Oxford, 2014 代理商:滄海書局.
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授課教師 應用化學系 王建隆老師
課程學分 4學分
授課年度 106學年度
授課對象 大學生
預備知識 物理、化學
課程提供 課程影音   課程綱要   課程行事曆 

週次課程內容課程影音課程下載
An outline of thermodynamics線上觀看MP4下載
Matter, element, atoms and zeroth law of thermodynamics線上觀看MP4下載
Introduction to molecular motion線上觀看MP4下載
Boltzmann distribution, equipartition theorem線上觀看MP4下載
The first law of thermodynamics線上觀看MP4下載
Heat capacity and microscopic of first law of thermodynamics線上觀看MP4下載
Enthalpy, function and variable線上觀看MP4下載
Thermochemistry線上觀看MP4下載
Calorimetry線上觀看MP4下載
Enthalpies of chemical change線上觀看MP4下載
Internal energy - changes in internal energy線上觀看MP4下載
Internal energy - changes at constant pressure線上觀看MP4下載
The Second law of thermodynamics線上觀看MP4下載
Carnot cycle線上觀看MP4下載
Entropy change for specific process線上觀看MP4下載
Boltzmann formula for the entropy線上觀看MP4下載
Spontaneous processes線上觀看MP4下載
Combing the First and Second Laws線上觀看MP4下載
Standard Gibbs energies線上觀看MP4下載
Physical transformations – chemical potential線上觀看MP4下載
Phase equilibria: one-component system (1/2)線上觀看MP4下載
Phase equilibria: one-component system (2/2)線上觀看MP4下載
Phase equilibria: multi-component system線上觀看MP4下載
Thermodynamics of mixing線上觀看MP4下載
The Thermodynamic of ideal solution線上觀看MP4下載
The Thermodynamic of real solution線上觀看MP4下載
Phase diagram (1/2)線上觀看MP4下載
Phase diagram (2/2)線上觀看MP4下載
Ionic solution線上觀看MP4下載
Colligative Properties線上觀看MP4下載
Chemical transformation, Equilibrium constant and Electrochemical cell線上觀看MP4下載

課程目標

本課程談論化學熱力學,熱力學討論熱或能量流動所造成的系統變化。在巨觀上將討論internal energy (U), enthalpy (H), entropy (S), free energy (G)與系統變化的關係,而微觀上則將介紹系統能量變化對分子運動與系統亂度的影響。在清楚了解U,H,S,G等熱力學參數後,則將進一步提升系統的複雜度,討論如何使用熱力學參數描述多組成(multiple components)或多相(multiple phases)並存系統的的變化與平衡。本課程將藉上課及作業協助學生建立熱力學觀念,並學習使用熱力學參數來對系統與變化進行描述。

 

課程章節

章節內容
The properties of gases-Pressure (P), Volume (V) and Temperature (T)
The zeroth law of thermodynamics & Kelvin temperature scale
The first law of thermodynamics-
1. Heat, Work, and energy.
2. Internal energy, enthalpy
3. heat capacity and internal pressure
Thermochemistry
The second law of thermodynamics- Heat energy & the concept of entropy
Equilibrium and spontaneity The third law of thermodynamics-entropy of perfect crystal at 0 K
Entropy changes for specific processes
The Helmholtz and Gibbs free energies
Combining the First and Second Laws
The Helmholtz and Gibbs free energies
Phase equilibrium
Physical transformations, mixing, and Colligative properties
Chemical equilibrium
The response of equilibria to the conditions
Electrochemical cells
Statistical thermodynamics


課程書目

Physical Chemistry- Quanta, Matter, and Change, 2nd Ed. Peter Atkins, Julio de Paula, Ronald Friedman Oxford, 2014 代理商:滄海書局.

 

評分標準

項目百分比
第一次期中考25%
第二次期中考30%
期末考30%
出席率15%

本課程行事曆提供課程進度與考試資訊參考。

學期週次
上課日期
參考課程進度

第一週

2017/09/12
  • The properties of gases-Pressure (P), Volume (V) and Temperature (T)
2017/09/14
第二週2017/09/19
  • The zeroth law of thermodynamics & Kelvin temperature scale
2017/09/21
第三週2017/09/26
  • The first law of thermodynamics-
    1. Heat, Work, and energy.
    2. Internal energy, enthalpy
    3. heat capacity and internal pressure
2017/09/28
第四週2017/10/03
  • Thermochemistry
2017/10/05
第五週2017/10/10
  • The second law of thermodynamics-
    Heat energy & the concept of entropy
2017/10/12
第六週2017/10/17
  • 1. Equilibrium and spontaneity
    2. The third law of thermodynamics-entropy of perfect crystal at 0 K
2017/10/19
第七週2017/10/24
  • Entropy changes for specific processes
2017/10/26
第八週2017/10/31
  • The Helmholtz and Gibbs free energies
2017/11/02
第九週2016/11/07
  • Combining the First and Second Laws
2017/11/09
第十週2016/11/14
  • Phase equilibrium
2016/11/16
第十一週2016/11/21
  • Physical transformations, mixing, and Colligative properties
2016/11/23
第十二週2016/11/28
  • Chemical equilibrium
2016/11/30
第十三週2016/12/05
  • The response of equilibria to the conditions
2016/12/07
第十四週2016/12/12
  • Electrochemical cells-1
2016/12/14
第十五週2016/12/19
  • Electrochemical cells-2
2016/12/21
第十六週2016/12/26
  • Statistical thermodynamics-1
2016/12/28
第十七週2017/01/02
  • Statistical thermodynamics-2
2017/01/04
第十八週2017/01/09
  • 期末考
2017/01/11