Physical Chemistry I
本課程是由 國立陽明交通大學應用化學系提供。
本學期將使學生瞭解化學熱力學的基礎觀念及應用 ，並藉上課及作業訓練學生建立觀念及培養學生獨立思考的能力，希望同學在學習後能墊定扎實的化學基礎。
Textbook：Physical Chemistry, R. G. Mortimer, 3rd Ed. Academic Press (2008)，偉明圖書.
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| Instructor(s) | Department of Applied Chemistry Prof. Yuan-Pern Lee |
|---|---|
| Course Credits | 4 Credits |
| Academic Year | Video: filmed in the 97 Academic Year, 2nd revisions in the 99 Academic Year; Lecture: updated in the 99 Academic Year |
| Level | Second year university student |
| Prior Knowledge | Physics, Chemistry, Applied Mathematics |
| Related Resources | Course Video Course Syllabus Course Calendar Course Handout |
| Week | Course Content | Course Video |
|---|---|---|
| 課程概述：如何學好物理化學 | Watch Online | |
| 導論：物理化學各領域的關係 | Watch Online | |
| 第一章 Systems, States, and Processes 1-1-1-2 一些基本的單位定義及觀念 | Watch Online | |
| 1-3 對氣體的描述：理想氣體及真實氣體 | Watch Online | |
| 1-4 PVT surface及臨界點 | Watch Online | |
| 1-5 熱力學所需之數學 | Watch Online | |
| 第二章 The Equilibrium Macroscopic States of Gases and Liquids 2-1-2-2 熱力學的簡單發展史及功與熱 | Watch Online | |
| 2-3 Internal Energy：The First Law of Thermodynamics 2-4 Calculation of Amounts of Heat and Energy Changes 2-5 Enthalpy | Watch Online | |
| 2-5 Enthalpy 2-6 Application to Ideal Gas 2-7 Application to Non-Ideal Gas | Watch Online | |
| 2-8 Calculation of Enthalpy Changes of Process without Chemical Reaction | Watch Online | |
| 第三章 Second and Third Laws of Thermodynamics: Entropy 3-1 The Second Law of Thermodynamics and the Carnot Engine | Watch Online | |
| 3-2 The Mathematical Statement of the Second Law: Entropy | Watch Online | |
| 3-3 The Calculation of Entropy Changes 3-4 Statistical Entropy 3-5 Third Law of Thermodynamics and Absolute Entropies | Watch Online | |
| 第四章 The Second and Third Laws of Thermodynamics：Entropy 4.1-4.2 G(Gibbs)和A(Helmholtz)自由能及動力學的基礎公式 | Watch Online | |
| 4-4 Gibbs Energy Calculation | Watch Online | |
| 4-5 Multicomponent System 4-6 Euler's Theorem and the Gibbs-Duhem Relation | Watch Online | |
| 第五章 The Thermodynamics of Real Systems 5-1 The Fundamental Fact of Phase Equilibrium 5-2 The Gibbs Phase Rule 5-3 Phase equilibrium in 1-component systems 5-4 The Gibbs Energy and Phase Transitions | Watch Online | |
| 5-4 The Gibbs Energy and Phase Transitions 5-5 Surface in One-Component System | Watch Online | |
| 第六章 The Thermodynamics of Solutions 6-1 Ideal Solutions | Watch Online | |
| 6-2 Henrys Law and Dilute Nonelectrolyte Solution 6-3 Activity and activity coefficients | Watch Online | |
| 6-5 Thermodynamic Functions of Nonideal Solutions 6-6 Phase Diagrams of Non-ideal mixtures 6-7 Colligative (tied together) Properties(依數性質) | Watch Online | |
| 第七章 Chemical Equilibrium 7-1 ΔG and the Equilibrium Constant 7-2 Reactions Involving Gases and Pure Solids or Liquids 7-3 Chemical Equilibrium in Solutions | Watch Online | |
| 7-4 Debye-Hückel Theory 7-5 Buffer Solutions 7-6 Temp. Dependence 7-7 Biological Systems | Watch Online | |
| 第八章 The Thermodynamics of Electrochemical Systems 8-1 The Chemical Potential and the Electric Potential 8-2 Electrochemical Cells 8-3 Half-cell Potentials and Cell Potentials | Watch Online | |
| 8-4 Determination of a± and g ± of Electrolytes 8-5 Determination of pH 8-6 Thermodynamic for Electrochemistry 8-6 Ion Mobility and Transference Number (補充) | Watch Online |
課程目標
本課程上課較為進階，以理學院學士班學生為優先。藉上課及作業訓練學生建立觀念及培養學生獨立思考的能力，並使學生瞭解化學熱力學的基礎觀念及應用。
課程章節
| 章節 | 章節內容 |
| 第一章 | Systems, States, and Processes |
| 第二章 | The Equilibrium Macroscopic States of Gases and Liquids |
| 第三章 | Work, Heat, and Energy：The First Law of Thermodynaics |
| 第四章 | The Second and Third Laws of Thermodynamics：Entropy |
| 第五章 | The Thermodynamics of Real Systems |
| 第六章 | Phase Equilbrium |
| 第七章 | Multicomponent Systems |
| 第八章 | The Thermodynamics of Chemical Equilibrium |
| 第九章 | The Thermodynamics of Electrical Systems |
課程書目
Physical Chemistry, R. G. Mortimer, 3rd Ed. Academic Press (2008)，偉明圖書。
參考書目
P. W. Atkins, "Physical Chemistry", 7th Ed., 2002, Oxford.
R. A. Alberty & R. J. Silbey, "Physical Chemistry", 4th Ed., Wiley, 2005.
I. N. Levine, "Physical Chemistry", 5th Ed., 2002.
J. S. Winn, "Physical Chemistry", 1st Ed., 1995, Harper Collins.
J. H. Noggle, "Physical Chemistry", 3rd Ed., Scott/Foresman, 1996 (Mathcad).
I. M. Klotz & R. M. Rosenberg, "Chemical Thermodynamics", 6th Ed., Wiley, 2000. (建議初學者研讀)
G. N. Lewis & M. Randall (Revised by K. S. Pitzer & L. Brewer), "Thermodynamics", 1961. (進階者用)
H. B. Callen, "Thermodynamics", 1960 (1988). (由數學觀點處理)
R. S. Berry, S. A. Rice, and J. Ross, "Physical Chemistry", 1980, Wiley. (進階)
I. Tinoco et al. "Physical Chemistry: Principles and Applications in Biological Sciences", 4th Ed., 2001. (生科應用)
評分標準
| 項目 | 百分比 |
| 第一次小考 (第1-3章(10/14；考1小時)) | 10% |
| 期中考 (第1-4章(11/3；19:00~24:00)) | 30% |
| 第二次小考 (第5-7章 (12/23；考2小時)) | 15% |
| 期末考 (第5-9章(1/12；19:00~24:00)) | 40% |
| 作業 | 15% |
本課程行事曆提供課程進度與考試資訊參考。
學期週次 | 上課日期 | 參考課程進度 |
第一週 | 09/12, 09/16 |
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| 第二週 | 09/22, 09/23 |
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| 第三週 | 09/29, 09/30 |
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| 第四週 | 10/06, 10/07 |
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| 第五週 | 10/13, 10/14 |
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| 第六週 | 10/20, 10/21 |
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| 第七週 | 10/27, 10/28 |
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| 第八週 | 11/03, 11/04 |
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| 第九週 | 11/10, 11/11 |
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| 第十週 | 11/17, 11/18 |
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| 第十一週 | 11/24, 11/25 |
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| 第十二週 | 12/01, 12/02 |
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| 第十三週 | 12/08, 12/09 |
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| 第十四週 | 12/15, 12/16 |
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| 第十五週 | 12/22, 12/23 |
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| 第十六週 | 12/29, 12/30 |
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| 第十七週 | 01/05, 01/06 |
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| 第十八週 | 01/12, 01/13 |
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