單元二 Equilibrium statistical mechanics I. Probability distribution, Most probable distribution, The molecular partition function, Translational partition function
| Week | Course Content | Course Video |
|---|---|---|
| 單元一 Molecular energy levels for macroscopic thermodynamics Introduction Quantum statistic mechanics Simple translational, rotational, and vibrational models Partition function | Watch Online | |
| 單元二 Equilibrium statistical mechanics I. Probability distribution Most probable distribution The molecular partition function Translational partition function | Watch Online | |
| Rotational partition function Vibrational partition function Electronic partition function Partition function for polyatomic molecule Number of translational states* | Watch Online | |
| 單元三 Equilibrium statistical mechanicsII Statistical thermodynamics Entropy Pressure State functions Calculation of internal energy Partition function of Van der Waals equation* | Watch Online | |
| Calculation example Chemical equilibrium | Watch Online | |
| Chemical reaction for triatomic system Arrhenius formula | Watch Online | |
| 單元四 Equilibrium statistical mechanics III. Ensembles Canonical ensemble Classical statistical mechanics | Watch Online | |
| Dense gases Liquids | Watch Online | |
| 單元五 The structure of solids, liquids, and polymers Crystal Vibration Free electron theory | Watch Online | |
| From solid to liquid Polymer conformation | Watch Online | |
| 單元六 The kinetic theory of gases The velocity probability distribution | Watch Online | |
| Radial distribution molecular speed Pressure, effusion and collision Potential energy | Watch Online | |
| Molecular collisions in a hard-sphere gas 單元七 The rates of chemical reactions Chemical reaction rate Forward reaction with one reactant | Watch Online | |
| Forward reaction with two reactants Including reverse reaction Competing reactions | Watch Online | |
| 單元八 The chemical reaction mechanisms Collision theory of bimolecular reactions Arrhenius formula (again) Fraction number in bimolecular reactions Unimolecular reactions | Watch Online | |
| Two-step reactions More than two-step reactions Chain reactions | Watch Online |
COURSE
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