Thermodynamics of Materials(II) - 101 Academic Year
本課程是由 國立陽明交通大學材料科學與工程學系提供。
Textbook：Introduction to the thermodynamics of materials, David Gaskell, 5th edition.
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| Instructor(s) | Department Of Materials Science And Engineering Prof. Yuan-Chieh Tseng |
|---|---|
| Course Credits | 3 Credits |
| Academic Year | 101 Academic Year |
| Level | College Students |
| Prior Knowledge | |
| Related Resources | Course Video Course Syllabus Course Calendar |
| Week | Course Content | Course Video |
|---|---|---|
| Week 01 | 複習材料熱力學(一)三大定律 Maxwell equations, four thermodynsmics potentials 第七章相圖平衡 | Watch Online |
| Week 02 | 第七章相圖平衡概念介紹 (1/3) | Watch Online |
| Week 02 | 第七章相圖平衡概念介紹 (2/3) | Watch Online |
| Week 03 | 第七章相圖平衡概念介紹 (3/3) | Watch Online |
| Week 03 | 第八章氣體分子行為簡介 P-V-T 之間的相互關係 理想氣體-非理想氣體行為之修正 | Watch Online |
| Week 04 | 較複雜之雙元、三元相圖概念解說 定溫、定壓下相圖變化概念建立 | Watch Online |
| Week 04 | 凡得瓦爾氣體介紹 非真實氣體之熱力學行為之量測 Heat of mixing and entropy of mixing of ideal gases 基本理論計算介紹 | Watch Online |
| Week 05 | Heat of mixing and entropy of mixing of ideal gases 基本理論計算介紹 | Watch Online |
| Week 05 | 第八章總結 | Watch Online |
| Week 06 | 第九章液體之行為簡介 Henry's La, Raoul's law 簡介 | Watch Online |
| Week 06 | Henry's La, Raoul's law 簡介 理想溶液、非理想溶液之觀念建立；以及其生成熱之觀念建立 | Watch Online |
| Week 07 | 理想溶液、非理想溶液之觀念建立;以及其生成熱之觀念建立 Gibbs-Duhen equation 簡介 | Watch Online |
| Week 07 | Gibbs-Duhen equation 簡介 Gibbs Free energy 之概念介紹 | Watch Online |
| Week 09 | 第九章總結 | Watch Online |
| Week 09 | 第十章 Gibbs free energy 運用在材料相圖之觀念建立；Regular solution，以及其在統計力學的觀點介紹 | Watch Online |
| Week 10 | Regular solution, 以及其在統計力學的觀點介紹 | Watch Online |
| Week 10 | 第十章 Gibbs free energy 運用在材料相圖之觀念建立 (1/3) | Watch Online |
| Week 11 | 第十章 Gibbs free energy 運用在材料相圖之觀念建立 (2/3) | Watch Online |
| Week 11 | 第十章 Gibbs free energy 運用在材料相圖之觀念建立 (3/3) | Watch Online |
| Week 12 | 自由能在自旋電子學中之應用介紹 | Watch Online |
| Week 13 | 第十一章 液態及固態材料標準態之觀念建立 相圖Gibbs free energy 繪製之練習 | Watch Online |
| Week 14 | 相圖對P, V, T 之變化行為及對應之 Gibbs Free Energy 觀念介紹 第十二章 氣體行為之介紹 (一) | Watch Online |
| Week 14 | 第十二章 氣體行為之介紹 | Watch Online |
| Week 15 | 第十二章 pure condensed and gaseous phase 反應簡介 | Watch Online |
| Week 15 | 第十二章計算範例示範 (1/2) | Watch Online |
| Week 16 | 第十二章計算範例示範 (2/2) | Watch Online |
課程章節
| 章節 | 章節內容 |
| Phase equilibrium in a one component system (Chapter 7 of Gaskell) | Gibbs free energy phase diagram, phase equilibrium Clasusuis-Clapeyron equation |
| The behaviors of gas (Chapter 8 of Gaskell) | Ideal and real gases comparison Use compression to observe real gas behaviors Van Der Waals model and a P-V diagram for a real gas Gas mixing, partial molar quantity fugacity |
| The behaviors of solution (Chapter 9 of Gaskell) | Evaporation to construct the concepts for solution behaviors Bonding effects and solution behaviors Activity to realize the ideality of solution behaviors Mixing of ideal and non-ideal solutions Gibbs-Duhem equation |
| Gibbs free energy, composition and phase diagram of binary systems (Chapter 10 of Gaskell) | Definition of regular solutions Gibbs free energy, phase stability, phase diagram of a regular solution (single and mixed cases) Relations among Gibbs free energy, activity, and standard state Equilibrium between solid and liquid phases, from G-x plot to mathematical expression Insoluble & eutectic phase diagram, ∆G, ∆S calculations |
| Reactions involving gases (Chapter 11 of Gaskell) | Reactions of gases Equilibrium constant Temperature and pressure effects on equilibrium of gases |
| Reactions involving condensed phases and gaseous phases (Chapter 12 of Gaskell) | Solid-gas phase equilibrium and Gibbs free energy calculation Ellingham diagram Melting effects on Ellingham diagram Mixing reaction effects on Ellingham diagram Pressure effects on Ellingham diagram |
| Phase diagrams (Chapter 13 & 14 of Gaskell) | 2-dimensional binary phase diagram 3-dimensional binary phase diagrams Ternary phase diagrams |
課程書目
Introduction to the thermodynamics of materials, David R, Gaskell, 5th edition
評分標準
| 項目 | 百分比 |
| Attendance | 5% |
| Midterms | 20%+20% |
| Homework | 10% |
| Quiz | 10% |
| Final | 35% |
本課程行事曆提供課程進度與考試資訊參考。
學期週次 | 上課日期 | 參考課程進度 |
第一週 | 02/18、02/19 |
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| 第二週 | 02/25、02/26 |
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| 第三週 | 03/04、03/05 |
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| 第四週 | 03/11、03/12 |
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| 第五週 | 03/18、03/19 |
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| 第六週 | 03/25、03/26 |
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| 第七週 | 04/01、04/02 |
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| 第八週 | 04/08、04/09 |
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| 第九週 | 04/15、04/16 |
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| 第十週 | 04/22、04/23 |
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| 第十一週 | 04/29、04/30 |
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| 第十二週 | 05/06、05/07 |
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| 第十三週 | 05/13、05/14 |
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| 第十四週 | 05/20、05/21 |
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| 第十五週 | 05/27、05/28 |
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| 第十六週 | 06/03、06/04 |
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| 第十七週 | 06/10、06/11 |
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| 第十八週 | 06/17、06/18 |
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COURSE
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